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Register a new userNonlinear bending of molecular films by polarized light
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A theory of photoinduced directed bending of non-crystalline molecular films is presented. Our approach is based on elastic deformation of the film due to interaction between molecules ordered through polarized light irradiation. The shape of illuminated film is obtained in the frame of the nonlinear elasticity theory. It is shown that the shape and the curvature of the film depend on the polarization and intensity of the light. The curvature of an irradiated film is a non-monotonic function of the extinction coefficient.
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We report on the results of a molecular dynamics simulation study of binodal glassy systems, formed in the process of isochoric rapid quenching from a high-temperature fluid phase. The transition to vitreous state occurs due to concurrent spinodal decomposition and solidification of the matter. The study is focused on topographies of the porous solid structures and their dependence on temperature and average density. To quantify the pore-size distributions, we put forth a scaling relation that provides a robust data collapse in systems with high porosity. We also find that the local density of glassy phases is broadly distributed, and, with increasing average glass density, a distinct peak in the local density distribution is displaced toward higher values.
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