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Register a new userHigh pressure behavior of Ga-doped LaMnO_3: a combined X-ray diffraction and optical spectroscopy study
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M. Baldini
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The pressure effects on the JT distortion of three representative compounds belonging to the LaMn_1-xGa_xO_3 (x= 0.2, 0.3, 0.4) family was widely investigated by means of X-ray diffraction and Raman spectroscopy. A compound with a fully JT distorted structure (x=0.2), one with regular octahedra (x=0.6) and one in an intermediate configuration (x=0.3) were selected. A pressure induced transitions from the orthorhombic Pbnm phase towards structures with higher symmetry were observed in all the samples. Both Raman and X-ray data confirm that the most important structural effect of pressure is that of reducing the octahedral distortion. The appearance of a feature in the lattice parameter behavior connected to a structural instability was also detected, pointing out the key role of the JT distortion in stabilizing the manganite structures. On the other hand, the complete suppression of the JT distortion in the high-pressure phases cannot be claimed. The Raman spectra collected from more distorted compounds (x=0.2, 0.3) reveal clearly the coexistence of domains of distorted and more regular octahedra in a certain pressure range. The first sketch of the Pressure vs. Ga-content phase diagram was drawn.
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Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition Li0.12Na0.88NbO3 (LNN12) using a combination of powder x-ray and neutron diffraction techniques in the temperature range 300 - 1100 K. Detailed Rietveld analyses of thermo-diffractograms show a variety of structural phase transitions ranging from non-polar antiferrodistortive to ferroelectric in nature. In the temperature range of 525 K to 675 K, unambiguous experimental evidence is shown for phase coexistence of orthorhombic paraelectric O1 phase (space group Cmcm) and orthorhombic ferroelectric O2 phase (space group Pmc21). The bp primitive lattice parameter of the ferroelectric orthorhombic phase (O2 phase) decreases, while the ap and cp primitive lattice parameters show normal increase with increase in temperature. Above 675 K, in the O1 phase, all lattice parameters come close to each other and increase continuously with increase of temperature, and around 925 K, ap parameter approaches bp parameter and thus the sample undergoes an orthorhombic to tetragonal phase transition. Further as temperature increases, the cp lattice parameter decreases, and finally approaches to ap parameter, and the sample transform into the cubic phase. The continuous change in the lattice parameters reveals that the successive phase transformations from orthorhombic O1 to high temperature tetragonal phase and finally to the cubic phase are not of a strong first order type in nature. We argue that application of chemical pressure as a result of Li substitution in NaNbO3 matrix, favours the freezing of zone centre phonons over the zone boundary phonons that are known to freeze in pure NaNbO3 as function of temperature.
The temperature and pressure dependence of the thermal displacements and lattice parameters were obtained across the $gamma to alpha$ phase transition of Ce using high-pressure, high-resolution neutron and synchrotron x-ray powder diffraction. The estimated vibrational entropy change per atom in the $gamma to alpha$ phase transition, $Delta S^{gamma - alpha}_{rm vib} approx (0.75 pm 0.15)$k$_{rm B}$, is about half of the total entropy change. The bulk modulus follows a power-law pressure dependence which is well described using the framework of electron-phonon coupling. These results clearly demonstrate the importance of lattice vibrations, in addition to the spin and charge degrees of freedom, for a complete description of the $gamma to alpha$ phase transition in elemental Ce.
YbBiPt is a heavy-fermion compound possessing significant short-range antiferromagnetic correlations below a temperature of $T^{textrm{*}}=0.7$ K, fragile antiferromagnetic order below $T_{rm{N}}=0.4$ K, a Kondo temperature of $T_{textrm{K}} approx1$ K, and crystalline-electric-field splitting on the order of $E/k_{textrm{B}}=1,textrm{-},10$ K. Whereas the compound has a face-centered-cubic lattice at ambient temperature, certain experimental data, particularly those from studies aimed at determining its crystalline-electric-field scheme, suggest that the lattice distorts at lower temperature. Here, we present results from high-resolution, high-energy x-ray diffraction experiments which show that, within our experimental resolution of $approx6,textrm{-},10times10^{-5}$ AA, no structural phase transition occurs between $T=1.5$ and $50$ K. In combination with results from dilatometry measurements, we further show that the compounds thermal expansion has a minimum at $approx18$ K and a region of negative thermal expansion for $9<T<18$ K. Despite diffraction patterns taken at $1.6$ K which indicate that the lattice is face-centered cubic and that the Yb resides on a crystallographic site with cubic point symmetry, we demonstrate that the linear thermal expansion may be modeled using crystalline-electric-field level schemes appropriate for Yb$^{3+}$ residing on a site with either cubic or less than cubic point symmetry.
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