Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userScaling theory for diffusion limited cluster aggregation in a porous medium
183
0
0.0
(
0
)
Authors
Patrick B. Warren
Ask ChatGPT about the research
No Arabic abstract
A scaling theory is developed for diffusion-limited cluster aggregation in a porous medium, where the primary particles and clusters stick irreversibly to the walls of the pore space as well as to each other. Three scaling regimes are predicted, connected by smooth crossovers. The first regime is at low primary particle concentrations where the primary particles stick individually to the walls. The second regime is at intermediate concentrations where clusters grow to a certain size, smaller than the pore size, then stick individually to the walls. The third regime is at high concentrations where the final state is a pore-space-filling network.
rate research
Read More
We discuss the scaling of characteristic lengths in diffusion limited aggregation (DLA) clusters in light of recent developments using conformal maps. We are led to the conjecture that the apparently anomalous scaling of lengths is due to one slow crossover. This is supported by an analytical argument for the scaling of the penetration depth of newly arrived random walkers, and by numerical evidence on the Laurent coefficients which uniquely determine each cluster. We find a single crossover exponent of -0.3 for all the characteristic lengths in DLA. This gives a hint about the structure of the renormalization group for this problem.
Diffusion-limited aggregation is consistent with simple scaling. However, strong subdominant terms are present, and these can account for various earlier claims of anomalous scaling. We show this in detail for the case of multiscaling.
A microscopic model of the effect of unbinding in diffusion limited aggregation based on a cellular automata approach is presented. The geometry resembles electrochemical deposition - ``ions diffuse at random from the top of a container until encountering a cluster in contact with the bottom, to which they stick. The model exhibits dendritic (fractal) growth in the diffusion limited case. The addition of a field eliminates the fractal nature but the density remains low. The addition of molecules which unbind atoms from the aggregate transforms the deposit to a 100% dense one (in 3D). The molecules are remarkably adept at avoiding being trapped. This mimics the effect of so-called ``leveller molecules which are used in electrochemical deposition.
We performed extensive numerical simulation of diffusion-limited aggregation in two dimensional channel geometry. Contrary to earlier claims, the measured fractal dimension D = 1.712 +- 0.002 and its leading correction to scaling are the same as in the radial case. The average cluster, defined as the average conformal map, is similar but not identical to Saffman-Taylor fingers.
We propose a unifying, analytical theory accounting for the self-organization of colloidal systems in nano- or micro-cluster phases. We predict the distribution of cluter sizes with respect to interaction parameters and colloid concentration. In particular, we anticipate a proportionality regime where the mean cluster size grows proportionally to the concentration, as observed in several experiments. We emphasize the interest of a predictive theory in soft matter, nano-technologies and biophysics.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
