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Register a new userMacroscopic proof of the Jarzynski-Wojcik fluctuation theorem for heat exchange
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In a recent work, Jarzynski and Wojcik (2004 Phys. Rev. Lett. 92, 230602) have shown by using the properties of Hamiltonian dynamics and a statistical mechanical consideration that, through contact, heat exchange between two systems initially prepared at different temperatures obeys a fluctuation theorem. Here, another proof is presented, in which only macroscopic thermodynamic quantities are employed. The detailed balance condition is found to play an essential role. As a result, the theorem is found to hold under very general conditions.
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We examine the Hall conductivity of macroscopic two-dimensional quantum system, and show that the observed quantities can sometimes violate the fluctuation dissipation theorem (FDT), even in the linear response (LR) regime infinitesimally close to equilibrium. The violation can be an order of magnitude larger than the Hall conductivity itself at low temperature and in strong magnetic field, which are accessible in experiments. We further extend the results to general systems and give a necessary condition for such large-scale violation to happen. This violation is a genuine quantum phenomenon that appears on a macroscopic scale. Our results are not only bound to the development of the fundamental issues of nonequilibrium physics, but the idea is also meaningful for practical applications, since the FDT is widely used for the estimation of noises from the LRs.
We use a relationship between response and correlation function in nonequilibrium systems to establish a connection between the heat production and the deviations from the equilibrium fluctuation-dissipation theorem. This scheme extends the Harada-Sasa formulation [Phys. Rev. Lett. 95, 130602 (2005)], obtained for Langevin equations in steady states, as it also holds for transient regimes and for discrete jump processes involving small entropic changes. Moreover, a general formulation includes two times and the new concepts of two-time work, kinetic energy, and of a two-time heat exchange that can be related to a nonequilibrium effective temperature. Numerical simulations of a chain of anharmonic oscillators and of a model for a molecular motor driven by ATP hydrolysis illustrate these points.
Stationary non-equilibrium states describe steady flows through macroscopic systems. Although they represent the simplest generalization of equilibrium states, they exhibit a variety of new phenomena. Within a statistical mechanics approach, these states have been the subject of several theoretical investigations, both analytic and numerical. The macroscopic fluctuation theory, based on a formula for the probability of joint space-time fluctuations of thermodynamic variables and currents, provides a unified macroscopic treatment of such states for driven diffusive systems. We give a detailed review of this theory including its main predictions and most relevant applications.
In recent letter [Phys.~Rev.~Lett {bf 123}, 110602 (2019)], Y.~Hasegawa and T.~V.~Vu derived a thermodynamic uncertainty relation. But the bound of their relation is loose. In this comment, through minor changes, an improved bound is obtained. This improved bound is the same as the one obtained in [Phys.~Rev.~Lett {bf 123}, 090604 (2019)] by A.~M.~Timpanaro {it et. al.}, but the derivation here is straightforward.
The Macroscopic Fluctuation Theory is an effective framework to describe transports and their fluctuations in classical out-of-equilibrium diffusive systems. Whether the Macroscopic Fluctuation Theory may be extended to the quantum realm and which form this extension may take is yet terra incognita but is a timely question. In this short introductory review, I discuss possible questions that a quantum version of the Macroscopic Fluctuation Theory could address and how analysing Quantum Simple Exclusion Processes yields pieces of answers to these questions.
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