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Stability of monolayers and bilayers in a copolymer-homopolymer blend model

122   0   0.0 ( 0 )
 Added by Yves van Gennip
 Publication date 2009
  fields Physics
and research's language is English




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We study the stability of layered structures in a variational model for diblock copolymer-homopolymer blends. The main step consists of calculating the first and second derivative of a sharp-interface Ohta-Kawasaki energy for straight mono- and bilayers. By developing the interface perturbations in a Fourier series we fully characterise the stability of the structures in terms of the energy parameters. In the course of our computations we also give the Greens function for the Laplacian on a periodic strip and explain the heuristic method by which we found it.



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We study a variational model for a diblock-copolymer/homopolymer blend. The energy functional is a sharp-interface limit of a generalisation of the Ohta-Kawasaki energy. In one dimension, on the real line and on the torus, we prove existence of minimisers of this functional and we describe in complete detail the structure and energy of stationary points. Furthermore we characterise the conditions under which the minimisers may be non-unique. In higher dimensions we construct lower and upper bounds on the energy of minimisers, and explicitly compute the energy of spherically symmetric configurations.
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