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Blistering of viscoelastic filaments

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 Added by Christian Wagner
 Publication date 2007
  fields Physics
and research's language is English




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When a dilute polymer solution experiences capillary thinning, it forms an almost uniformly cylindrical thread, which we study experimentally. In the last stages of thinning, when polymers have become fully stretched, the filament becomes prone to instabilities, of which we describe two: A novel breathing instability, originating from the edge of the filament, and a sinusoidal instability in the interior, which ultimately gives rise to a blistering pattern of beads on the filament. We describe the linear instability with a spatial resolution of 80 nm in the disturbance amplitude. For sufficiently high polymer concentrations, the filament eventually separates out into a solid phase of entangled polymers, connected by fluid beads. A solid polymer fiber of about 100 nanometer thickness remains, which is essentially permanent.



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A fluid dynamics video of the break up of a droplet of saliva is shown. First a viscoelastic filament is formed and than the blistering of this filament is shown. Finally, a flow induced phase separation takes place nanometer sized solid fiber remains that consist out of the biopolymers.
In this paper, a three-dimensional numerical solver is developed for suspensions of rigid and soft particles and droplets in viscoelastic and elastoviscoplastic (EVP) fluids. The presented algorithm is designed to allow for the first time three-dimensional simulations of inertial and turbulent EVP fluids with a large number particles and droplets. This is achieved by combining fast and highly scalable methods such as an FFT-based pressure solver, with the evolution equation for non-Newtonian (including elastoviscoplastic) stresses. In this flexible computational framework, the fluid can be modelled by either Oldroyd-B, neo-Hookean, FENE-P, and Saramito EVP models, and the additional equations for the non-Newtonian stresses are fully coupled with the flow. The rigid particles are discretized on a moving Lagrangian grid while the flow equations are solved on a fixed Eulerian grid. The solid particles are represented by an Immersed Boundary method (IBM) with a computationally efficient direct forcing method allowing simulations of a large numbers of particles. The immersed boundary force is computed at the particle surface and then included in the momentum equations as a body force. The droplets and soft particles on the other hand are simulated in a fully Eulerian framework, the former with a level-set method to capture the moving interface and the latter with an indicator function. The solver is first validated for various benchmark single-phase and two-phase elastoviscoplastic flow problems through comparison with data from the literature. Finally, we present new results on the dynamics of a buoyancy-driven drop in an elastoviscoplastic fluid.
Newtonian pipe flow is known to be linearly stable at all Reynolds numbers. We report, for the first time, a linear instability of pressure driven pipe flow of a viscoelastic fluid, obeying the Oldroyd-B constitutive equation commonly used to model dilute polymer solutions. The instability is shown to exist at Reynolds numbers significantly lower than those at which transition to turbulence is typically observed for Newtonian pipe flow. Our results qualitatively explain experimental observations of transition to turbulence in pipe flow of dilute polymer solutions at flow rates where Newtonian turbulence is absent. The instability discussed here should form the first stage in a hitherto unexplored dynamical pathway to turbulence in polymer solutions. An analogous instability exists for plane Poiseuille flow.
A modal stability analysis shows that plane Poiseuille flow of an Oldroyd-B fluid becomes unstable to a `center mode with phase speed close to the maximum base-flow velocity, $U_{max}$. The governing dimensionless groups are the Reynolds number $Re = rho U_{max} H/eta$, the elasticity number $E = lambda eta/(H^2rho)$, and the ratio of solvent to solution viscosity $eta_s/eta$; here, $lambda$ is the polymer relaxation time, $H$ is the channel half-width, and $rho$ is the fluid density. For experimentally relevant values (e.g., $E sim 0.1$ and $beta sim 0.9$), the predicted critical Reynolds number, $Re_c$, for the center-mode instability is around $200$, with the associated eigenmodes being spread out across the channel. In the asymptotic limit of $E(1 -beta) ll 1$, with $E$ fixed, corresponding to strongly elastic dilute polymer solutions, $Re_c propto (E(1-beta))^{-frac{3}{2}}$ and the critical wavenumber $k_c propto (E(1-beta))^{-frac{1}{2}}$. The unstable eigenmode in this limit is confined in a thin layer near the channel centerline. The above features are largely analogous to the center-mode instability in viscoelastic pipe flow (Garg et al., Phys. Rev. Lett., 121, 024502 (2018)), and suggest a universal linear mechanism underlying the onset of turbulence in both channel and pipe flows of suffciently elastic dilute polymer solutions.
126 - A. Chauhan , S. Gupta , C. Sasmal 2021
The flow of viscoelastic fluids in porous media is encountered in many practical applications, such as in the enhanced oil recovery process or in the groundwater remediation. Once the flow rate exceeds a critical value in such flows, an elastic instability with fluctuating flow field is observed, which ultimately transits to a more chaotic and turbulence-like flow structure as the flow rate further increases. In a recent study, it has been experimentally shown that this chaotic flow behaviour of viscoelastic fluids can be suppressed by increasing the geometric disorder in a model porous media consisting of a microchannel with several micropillars placed in it. However, the present numerical study demonstrates that this is not always true. We show that it depends on the initial arrangement of the micropillars for mimicking the porous media. In particular, we find that for an initial ordered and aligned configuration of the micropillars, the introduction of geometric order actually increases the chaotic flow dynamics as opposed to that seen for an initial ordered and staggered configuration of the micropillars. We suggest that this chaotic flow behaviour actually depends on the number of the stagnation points revealed to the flow field where maximum stretching of the viscoelastic microstructure happens. Our findings and explanation are perfectly in line with that observed and provided in a more recent experimental study.
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