This paper has been published in Bulletin of the Chemical Society of Japan, which can be viewed at the following URL: http://doi.org/10.1246/bcsj.20150110 Cs2SnI6, a variant of perovskite CsSnI3, is expected for a photovoltaic material. Based on a simple ionic model, it is expected that Cs2SnI6 is composed of Cs+, I-, and Sn4+ ions and that the band gap is primarily made of occupied I- 5p6 valence band maximum (VBM) and unoccupied Sn4+ 5s conduction band minimum (CBM) similar to SnO2. In this work, we performed density functional theory (DFT) calculations and revealed that the real oxidation state of the Sn ion in Cs2SnI6 is +2 similar to CsSnI3. The +2 oxidation state of Sn originates from 2 ligand holes in the [SnI6]2- octahedron unit, where the ligand [I6] cluster has the apparent [I66-L+2]4- oxidation state, because the band gap is formed mainly by occupied I 5p VBM and unoccupied I 5p CBM. The +2 oxidation state of Sn and the band gap are originated from the intracluster hybridization and stabilized by the strong covalent interaction between Sn and I.
Hadronic gamma-ray emission from supernova remnants (SNRs) is an important tool to test shock acceleration of cosmic ray protons. Tycho is one of nearly a dozen Galactic SNRs which are suggested to emit hadronic gamma-ray emission. Among them, however, it is the only one in which the hadronic emission is proposed to arise from the interaction with low-density (~0.3 cm^{-3}) ambient medium. Here we present an alternative hadronic explanation with a modest conversion efficiency (of order 1%) for this young remnant. With such an efficiency, a normal electron-proton ratio (of order 10^{-2}) is derived from the radio and X-ray synchrotron spectra and an average ambient density that is at least one-order-of-magnitude higher is derived from the hadronic gamma-ray flux. This result is consistent with the multi-band evidence of the presence of dense medium from the north to the east of the Tycho SNR. The SNR-cloud association, in combination with the HI absorption data, helps to constrain the so-far controversial distance to Tycho and leads to an estimate of 2.5 kpc.
To achieve high range resolution profile (HRRP), the geometric theory of diffraction (GTD) parametric model is widely used in stepped-frequency radar system. In the paper, a fast synthetic range profile algorithm, called orthogonal matching pursuit with sensing dictionary (OMP-SD), is proposed. It formulates the traditional HRRP synthetic to be a sparse approximation problem over redundant dictionary. As it employs a priori information that targets are sparsely distributed in the range space, the synthetic range profile (SRP) can be accomplished even in presence of data lost. Besides, the computational complexity is reduced by introducing sensing dictionary (SD) and it mitigates the model mismatch at the same time. The computation complexity decreases from O(MNDK) flops for OMP to O(M(N +D)K) flops for OMP-SD. Simulation experiments illustrate its advantages both in additive white Gaussian noise (AWGN) and noiseless situation, respectively.
The quantum anomalous Hall (QAH) state is a two-dimensional bulk insulator with a non-zero Chern number in absence of external magnetic fields. Protected gapless chiral edge states enable dissipationless current transport in electronic devices. Doping topological insulators with random magnetic impurities could realize the QAH state, but magnetic order is difficult to establish experimentally in the bulk insulating limit. Here we predict that the single quintuple layer of GdBiTe3 film could be a stoichiometric QAH insulator based on ab-initio calculations, which explicitly demonstrate ferromagnetic order and chiral edge states inside the bulk gap. We further investigate the topological quantum phase transition by tuning the lattice constant and interactions. A simple low-energy effective model is presented to capture the salient physical feature of this topological material.
We use planar coordinates as well as hyperbolic coordinates to separate the de Sitter spacetime into two parts. These two ways of cutting the de Sitter give rise to two different spatial infinities. For spacetimes which are asymptotic to either half of the de Sitter spacetime, we are able to provide definitions of the total energy, the total linear momentum, the total angular momentum, respectively. And we prove two positive mass theorems, corresponding to these two sorts of spatial infinities, for spacelike hypersurfaces whose mean curvatures are bounded by certain constant from above.
