Collinear laser spectroscopy has been performed on the $^{79}_{30}$Zn$_{49}$ isotope at ISOLDE-CERN. The existence of a long-lived isomer with a few hundred milliseconds half-life was confirmed, and the nuclear spins and moments of the ground and isomeric states in $^{79}$Zn as well as the isomer shift were measured. From the observed hyperfine structures, spins $I = 9/2$ and $I = 1/2$ are firmly assigned to the ground and isomeric states. The magnetic moment $mu$ ($^{79}$Zn) = $-$1.1866(10) $mu_{rm{N}}$, confirms the spin-parity $9/2^{+}$ with a $ u g_{9/2}^{-1}$ shell-model configuration, in excellent agreement with the prediction from large scale shell-model theories. The magnetic moment $mu$ ($^{79m}$Zn) = $-$1.0180(12) $mu_{rm{N}}$ supports a positive parity for the isomer, with a wave function dominated by a 2h-1p neutron excitation across the $N = 50$ shell gap. The large isomer shift reveals an increase of the intruder isomer mean square charge radius with respect to that of the ground state: $delta langle r^{2}_{c}rangle^{79,79m}$ = +0.204(6) fm$^{2}$, providing first evidence of shape coexistence.