We demonstrate that ultracold polyatomic symmetric top molecules, such as methyl fluoride, loaded into an optical lattice and subject to DC electric and microwave field dressing, can display topological order via a self-consistent analog of a proximity effect in the internal state space of the molecule. The non-trivial topology arises from pairwise transitions between internal states induced by dipole-dipole interactions and made resonant by the field dressing. Topological order is explicitly demonstrated by matrix product state simulations on 1D chains. Additionally, we show that in the limit of pinned molecules our description maps onto a long-range and anisotropic XYZ spin model, where Majorana fermions are zero-energy edge excitations in the case of nearest-neighbor couplings.
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