We present an observation of the very late thermal pulse object V4334 Sgr (Sakurais Object) with the Infrared Spectrometer (IRS) on the Spitzer Space Telescope. The emission from 5-38 microns is dominated by the still-cooling dust shell. A number of features are seen in absorption against the dust shell, which we attribute to HCN and polyyne molecules. We use these features to determine the 12C/13C ratio for the absorbing gas to be ~ 3.2 (+3.2,-1.6}; this implies that, despite the H-content of the molecules, the hydrocarbon-bearing gas must have originated in material produced in the very late thermal pulse. We see no evidence of emission lines, despite the recently-reported optical and radio observations that suggest the effective temperature of the stellar remnant is rising.