We report the discovery of a hot DQ white dwarf, NGC 2168:LAWDS 28, that is a likely member of the 150-Myr old cluster NGC 2168 (Messier 35). The spectrum of the white dwarf is dominated by CII features. The effective temperature is difficult to estimate but likely > 20,000 K based on the temperatures of hot DQs with similar spectra. NGC2168:LAWDS 28 provides further evidence that hot DQs may be the ``missing high-mass helium-atmosphere white dwarfs. Based on published studies, we find that the DBA WD LP 475-242 is likely a member of the Hyades open cluster, as often assumed. These two white dwarfs are the entire sample of known He-atmosphere white dwarfs in open clusters with turnoff masses >2 solar masses. Based on the number of known cluster DA white dwarfs and a redetermination of the H-atmosphere:He-atmosphere ratio, commonly known as the DA:DB ratio, we re-examine the hypothesis that the H- to He-atmosphere ratio in open clusters is the same as the ratio in the field. Under this hypothesis, we calculate that five He-atmosphere WDs are expected to have been discovered, with a probability of finding fewer than three He-atmosphere white dwarfs of 0.08, or at the ~ 2-sigma level.
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