As a vital problem in classification-oriented transfer, unsupervised domain adaptation (UDA) has attracted widespread attention in recent years. Previous UDA methods assume the marginal distributions of different domains are shifted while ignoring the discriminant information in the label distributions. This leads to classification performance degeneration in real applications. In this work, we focus on the conditional distribution shift problem which is of great concern to current conditional invariant models. We aim to seek a kernel covariance embedding for conditional distribution which remains yet unexplored. Theoretically, we propose the Conditional Kernel Bures (CKB) metric for characterizing conditional distribution discrepancy, and derive an empirical estimation for the CKB metric without introducing the implicit kernel feature map. It provides an interpretable approach to understand the knowledge transfer mechanism. The established consistency theory of the empirical estimation provides a theoretical guarantee for convergence. A conditional distribution matching network is proposed to learn the conditional invariant and discriminative features for UDA. Extensive experiments and analysis show the superiority of our proposed model.