Coexistence of superconductivity and antiferromagentic order in Er$_{2}$O$_{2}$Bi with anti-ThCr$_{2}$Si$_{2}$ structure


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We investigated the coexistence of superconductivity and antiferromagnetic order in the compound Er$_{2}$O$_{2}$Bi with anti-ThCr$_{2}$Si$_{2}$-type structure through resistivity, magnetization, specific heat measurements and first-principle calculations. The superconducting transition temperature $T_{rm c}$ of 1.23 K and antiferromagnetic transition temperature $T_{rm N}$ of 3 K are observed in the sample with the best nominal composition. The superconducting upper critical field $H_{rm c2}$(0) and electron-phonon coupling constant $lambda$$_{e-ph}$ in Er$_{2}$O$_{2}$Bi are similar to those in the previously reported non-magnetic superconductor Y$_{2}$O$_{2}$Bi with the same structure, indicating that the superconductivity in Er$_{2}$O$_{2}$Bi may have the same origin as in Y$_{2}$O$_{2}$Bi. The first-principle calculations of Er$_{2}$O$_{2}$Bi show that the Fermi surface is mainly composed of the Bi 6$p$ orbitals both in the paramagnetic and antiferromagnetic state, implying minor effect of the 4$f$ electrons on the Fermi surface. Besides, upon increasing the oxygen incorporation in Er$_{2}$O$_{x}$Bi, $T_{rm c}$ increases from 1 to 1.23 K and $T_{rm N}$ decreases slightly from 3 to 2.96 K, revealing that superconductivity and antiferromagnetic order may compete with each other. The Hall effect measurements indicate that hole-type carrier density indeed increases with increasing oxygen content, which may account for the variations of $T_{rm c}$ and $T_{rm N}$ with different oxygen content.

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