Quantum reading provides a general framework where to formulate the statistical discrimination of quantum channels. Several paths have been taken for such a problem. However, there is much to be done in the avenue of optimizing channel discrimination using classical codes. At least two open questions can be pointed to: how to construct low complexity encoding schemes that are interesting for channel discrimination and, more importantly, how to develop capacity-achieving protocols. The aim of this paper is to present a solution to these questions using polar codes. Firstly, we characterize the rate and reliability of the channels under polar encoding. We also show that the error probability of the scheme proposed decays exponentially with respect to the code length. Lastly, an analysis of the optimal quantum states to be used as probes is given.
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