High-frequency long-baseline experiments with the Atacama Large Millimeter/submillimeter Array were organized to test the high angular resolution imaging capabilities in the submillimeter wave regime using baselines up to 16 km. Four experiments were conducted, two Band 7 (289 GHz) and two Band 8 (405 GHz) observations. Phase correction using band-to-band (B2B) phase referencing was used with a phase calibrator only 0.7deg away observed in Band 3 (96 GHz) and Band 4 (135 GHz), respectively. In Band 8, we achieved the highest resolution of 14x11 mas. We compared the synthesis images of the target quasar using 20 and 60 s switching cycle times in the phase referencing. In Band 7, the atmosphere had good stability in phase rms (<0.5 rad over 2 minutes), and there was little difference in image coherence between the 20 and 60 s switching cycle times. One Band 8 experiment was conducted under a worse phase rms condition (>1 rad over 2 minutes), which led to a significantly reduced coherence when using the 60 s switching cycle time. One of our four experiments indicates that the residual phase rms error after phase referencing can be reduced to 0.16 rad at 289 GHz in using the 20 s switching cycle time. Such conditions would meet the phase correction requirement of image coherence of >70% in Band 10, assuming a similar phase calibrator separation angle, emphasizing the need for such B2B phase referencing observing at high frequencies.
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