With the help of quantum key distribution (QKD), two distant peers are able to share information-theoretically secure key bits. Increasing key rate is ultimately significant for the applications of QKD in lossy channel. However, it has proved that there is a fundamental rate-distance limit, named linear bound, which limits the performance of all existing repeaterless protocols and realizations. Surprisingly, a recently proposed protocol, called twin-field (TF) QKD can beat linear bound with no need of quantum repeaters. Here, we present the first implementation of TF-QKD protocol and demonstrate its advantage of beating linear bound at the channel distance of 300 km. In our experiment, a modified TF-QKD protocol which does not assume phase post-selection is considered, and thus higher key rate than the original one is expected. After well controlling the phase evolution of the twin fields travelling hundreds of kilometers of optical fibres, the implemented system achieves high-visibility single-photon interference, and allows stable and high-rate measurement-device-independent QKD. Our experimental demonstration and results confirm the feasibility of the TF-QKD protocol and its prominent superiority in long distance key distribution services.
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