Although regular semisimple Hessenberg varieties are smooth and irreducible, semisimple Hessenberg varieties are not necessarily smooth in general. In this paper we determine the irreducible components of semisimple Hessenberg varieties corresponding to the standard Hessenberg space. We prove that these irreducible components are smooth and give an explicit description of their intersections, which constitute the singular locus. We conclude with an example of a semisimple Hessenberg variety corresponding to another Hessenberg space which is singular and irreducible, showing that results of this nature do not hold for all semisimple Hessenberg varieties.