We give some classifications of biharmonic hypersurfaces with constant scalar curvature. These include biharmonic Einstein hypersurfaces in space forms, compact biharmonic hypersurfaces with constant scalar curvature in a sphere, and some complete biharmonic hypersurfaces of constant scalar curvature in space forms and in a non-positively curved Einstein space. Our results provide additional cases (Theorem 2.3 and Proposition 2.8) that supports the conjecture that a biharmonic submanifold in a sphere has constant mean curvature, and two more cases that support Chens conjecture on biharmonic hypersurfaces (Corollaries 2.2,2.7).