We consider a pentagon chain described by a Hubbard type of model considered under periodic boundary conditions. The system i) is placed in an external magnetic field perpendicular to the plane of the cells, and ii) is in a site selective manner under the action of an external electric potential. In these conditions we show in a non-approximated manner that the physical properties of the system can be qualitatively changed. The changes cause first strong modifications of the band structure of the system created by the one-particle part of the Hamiltonian, and second, considerably redraw the emergence domains of ordered phases. We exemplify this by deducing ferromagnetic ground states in the presence of external fields in two different domains of the parameter space.
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