We investigate the mutiphoton process between different Bloch states in an amplitude modulated optical lattice. In the experiment, we perform the modulation with more than one frequency components, which includes a high degree of freedom and provides a flexible way to coherently control quantum states. Based on the study of single frequency modulation, we investigate the collaborative effect of different frequency components in two aspects. Through double frequency modulations, the spectrums of excitation rates for different lattice depths are measured. Moreover, interference between two separated excitation paths is shown, emphasizing the influence of modulation phases when two modulation frequencies are commensurate. Finally, we demonstrate the application of the double frequency modulation to design a large-momentum-transfer beam splitter. The beam splitter is easy in practice and would not introduce phase shift between two arms.