Superconducting Properties of the K$_{{x}}$WO$_{3}$ Tetragonal Tungsten Bronze and the Superconducting Phase Diagram of the Tungsten Bronze Family


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We report the superconducting properties of the K$_{x}$WO$_{3}$ tetragonal tungsten bronze. The highest superconducting transition temperature ($T_{c}=2.1$K) was obtained for K$_{0.38}$WO$_{3}$. $T_{c}$ decreases linearly with increasing K content. Using the measured values for the upper critical field $H_{c2}$, and the specific heat $C$, we estimate the orbital critical field $H_{c2}$(0), coherence length $xi$(0), Debye temperature $Theta _{D}$ and coupling constant $lambda _{ep}$. The magnitude of the specific heat jump at $T_{c}$ suggests that the K$_{x}$WO$_{3}$ tetragonal tungsten bronze is a weakly-coupled superconductor. The superconducting phase diagram of the doped tungsten bronze family is presented.

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