We investigate the multi-wavelength properties of a sample of 450-mu m selected sources from the SCUBA-2 Cosmology Legacy Survey (S2CLS). A total of 69 sources were identified above 4sigma in deep SCUBA-2 450-mu m observations overlapping the UDS and COSMOS fields and covering 210 sq. arcmin to a typical depth of sigma 450=1.5 mJy. Reliable cross identification are found for 58 sources (84 per cent) in Spitzer and Hubble Space Telescope WFC3/IR data. The photometric redshift distribution (dN/dz) of 450mu m-selected sources is presented, showing a broad peak in the redshift range 1<z<3, and a median of z=1.4. Combining the SCUBA-2 photometry with Herschel SPIRE data from HerMES, the submm spectral energy distribution (SED) is examined via the use of modified blackbody fits, yielding aggregate values for the IR luminosity, dust temperature and emissivity of <LIR>=10^12 +/- 0.8 L_sol, <T_D>=42 +/- 11 K and <beta_D>=1.6 +/- 0.5, respectively. The relationship between these SED parameters and the physical properties of galaxies is investigated, revealing correlations between T_D and LIR and between beta_D and both stellar mass and effective radius. The connection between star formation rate and stellar mass is explored, with 24 per cent of 450 mu m sources found to be ``star-bursts, i.e. displaying anomalously high specific SFRs. However, both the number density and observed properties of these ``star-burst galaxies are found consistent with the population of normal star-forming galaxies.
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