A microwave field is used to control the interaction between pairs of optical photons stored in highly excited collective states (Rydberg polaritons). We show that strong dipole-dipole interactions induced by the microwave field destroy the coherence of polariton modes with more than one Rydberg excitation. Consequently single-polariton modes, which correspond to single stored photons, are preferentially retrieved from the sample. Measurements of the photon statistics of the retrieved light field also reveal non-trivial propagation dynamics of the interacting polaritons.
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