Interstellar polarization in the optical/infrared has long been known to be due to asymmetrical dust grains aligned with the magnetic field and can potentially provide a resource effective way to probe both the topology and strength of the magnetic field. However, to do so with confidence, the physics and variability of the alignment mechanisms must be quantitatively understood. The last 15 years has seen major advancements in both the theoretical and observational understanding of this problem. I here review the current state of the observational constraints on the grain alignment physics. While none of the three classes of proposed grain alignment theories: mechanical, paramagnetic relaxation and radiative alignment torque, can be viewed as having been empirically confirmed, the first two have failed some critical observational tests, whereas the latter has recently been given specific observational support and must now be viewed as the leading candidate.
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