We study how the properties of the four neutralino states, chi_i (i = 1, 2, 3, 4), can be investigated at the Large Hadron Collider (LHC), in the case when the lightest one, chi_1, has a mass m_chi < 50 GeV and is stable. This situation arises naturally in supersymmetric models where gaugino masses are not unified at a Grand Unified (GUT) scale and R-parity is conserved. The main features of these neutralino states are established by analytical and numerical analyses, and two scenarios are singled out on the basis of the cosmological properties required for the relic neutralinos. Signals expected at LHC are discussed through the main chain processes started by a squark, produced in the initial proton-proton scattering. We motivate the selection of some convenient benchmarks, in the light of the spectroscopical properties (mass spectrum and transitions) of the four neutralino states. Branching ratios and the expected total number of events are derived in the various benchmarks, and their relevance for experimental determination of neutralino properties is finally discussed.
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