Aims: We define the relationship between the double-mode pulsation of Cepheids and metallicity in a more accurate way, determine the empirical metallicities of double-mode Cepheids from homogeneous, high-resolution spectroscopic data, and study of the period-ratio -- metallicity dependence. Methods: The high S/N echelle spectra obtained with the FEROS spectrograph were analyzed using a self-developed IRAF script, and the iron abundances were determined by comparing with synthetic spectra assuming LTE. Results: Accurate [Fe/H] values of 17 galactic beat Cepheids were determined. All these stars have solar or slightly subsolar metallicity. Their period ratio P1/P0 shows strong correlation with their derived [Fe/H] values. The corresponding period ratio -- metallicity relation has been evaluated.
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