We present the 2nd version of the Catalogue of Radial Velocities with Astrometric Data (CRVAD-2). This is the result of the cross-identification of stars from the All-Sky Compiled Catalogue of 2.5 Million Stars (ASCC-2.5) with the General Catalogue of Radial Velocities and with other recently published radial velocity lists and catalogues. The CRVAD-2 includes accurate J2000 equatorial coordinates, proper motions and trigonometric parallaxes in the Hipparcos system, $B, V$ photometry in the Johnson system, spectral types, radial velocities (RVs), multiplicity and variability flags for 54907 ASCC-2.5 stars. We have used the CRVAD-2 for a new determination of mean RVs of 363 open clusters and stellar associations considering their established members from proper motions and photometry in the ASCC-2.5. For 330 clusters and associations we compiled previously published mean RVs from the literature, critically reviewed and partly revised them. The resulting Catalogue of Radial Velocities of Open Clusters and Associations (CRVOCA) contains about 460 open clusters and about 60 stellar associations in the Solar neighbourhood. These numbers still represent less than 30% of the total number of about 1820 objects currently known in the Galaxy. The mean RVs of young clusters are generally better known than those of older ones.
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