Overlap fermions are a powerful tool for investigating the chiral and topological structure of the vacuum and the thermal states of QCD. We study various chiral and topological aspects of the finite temperature phase transition of N_f=2 flavours of O(a) improved Wilson fermions, using valence overlap fermions as a probe. Particular emphasis is placed upon the analysis of the spectral density and the localisation properties of the eigenmodes as well as on the local structure of topological charge fluctuations in the vicinity of the chiral phase transition. The calculations are done on 16^3x8 lattices generated by the DIK collaboration.
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