We report on two sub-band transport in double gate SiO$_2$-Si-SiO$_2$ quantum well with 14 nm thick Si layer at 270 mK. At symmetric well potential the experimental sub-band spacing changes monotonically from 2.3 to 0.3 meV when the total density is adjusted by gate voltages between $sim 0.7times 10^{16}$ $-3.0times 10^{16}$ m$^{-2}$. The conductivity is mapped in large gate bias window and it shows strong non-monotonic features. At symmetric well potential and high density these features are addressed to sub-band wave function delocalization in the quantization direction and to different disorder of the top and bottom interfaces of the Si well. Close to bi-layer/second sub-band threshold the non-monotonic behavior is interpreted to arise from scattering from localized band tail electrons.
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