We report on a study of thermal Hall conductivity k_xy in the superconducting state of CeCoIn_5. The scaling relation and the density of states of the delocalized quasiparticles, both obtained from k_xy, are consistent with d-wave superconducting symmetry. The onset of superconductivity is accompanied by a steep increase in the thermal Hall angle, pointing to a striking enhancement in the quasiparticle mean free path. This enhancement is drastically suppressed in a very weak magnetic field. These results highlight that CeCoIn_5 is unique among superconductors. A small Fermi energy, a large superconducting gap, a short coherence length, and a long mean free path all indicate that CeCoIn_5 is clearly in the superclean regime (E_F/Delta<<l/xi), in which peculiar vortex state is expected.
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