Correlation between Tc and Lattice Parameters of Novel Superconducting NaxCoO2 yH2O


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We synthesized the five batches of the samples of the novel P3 type superconductor, Na$_{x}$(H$_{3}$O)$_{y}$CoO$_{2}cdot y$H$_{2}$O, by the soft chemical process starting from $alpha$-NaCoO$_{2}$. The chemical and structural properties varied rather widely from batch to batch, with a result that $T_{c}$ varied from 4.6 K to 3.2 K. The magnetic susceptibility above $T_{c}$ shows upturn at low temperature as in the case of the P2 phase. The $T_{c}$ seems to be well correlated to the lattice parameters.

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