We investigate interactions between electrons and nuclear spins by using the resistance (Rxx) peak which develops near filling factor n = 2/3 as a probe. By temporarily tuning n to a different value, ntemp, with a gate, the Rxx peak is shown to relax quickly on both sides of ntemp = 1. This is due to enhanced nuclear spin relaxation by Skyrmions, and demonstrates the dominant role of nuclear spin in the transport anomaly near n = 2/3. We also observe an additional enhancement in the nuclear spin relaxation around n = 1/2 and 3/2, which suggests a Fermi sea of partially-polarized composite fermions.