High resolution spectropolarimetry of the Deep Impact target, comet 9P/ Tempel 1, was performed during the impact event on July 4th, 2005 with the HiVIS Spectropolarimeter and the AEOS 3.67m telescope on Haleakala, Maui. We observed atypical polarization spectra that changed significantly in the few hours after the impact. The polarization of scattered light as a function of wavelength is very sensitive to the size and composition (complex refractive index) of the scattering particles as well as the scattering geometry. As opposed to most observations of cometary dust, which show an increase in the linear polarization with the wavelength (at least in the visible domain and for phase angles greater than about 30%, a red polarization spectrum) observations of 9P/Tempel 1 at a phase angle of 41 degrees beginning 8 minutes after impact and centered at 6:30UT showed a polarization of 4% at 650 nm falling to 3% at 950 nm. The next observation, centered an hour later showed a polarization of 7% at 650 nm falling to 2% at 950nm. This corresponds to a spectropolarimetric gradient, or slope, of -0.9% per 1000 Angstroms 40 minutes after impact, decreasing to a slope of -2.3% per 1000 Angstroms an hour and a half after impact. This is an atypical blue polarization slope, which became more blue 1 hour after impact. The polarization values of 4% and 7% at 650nm are typical for comets at this scattering angle, whereas the low polarization of 2% and 3% at 950nm is not. We compare observations of comet 9P/Tempel 1 to that of a typical comet, C/2004 Machholz, at a phase angle of 30 degrees which showed a typical red slope, rising from 2% at 650nm to 3% at 950nm in two different observations (+1.0 and +0.9% per 1000 Angstroms).
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