Gamma-ray bursts (GRBs) and their afterglows have been proposed as an excellent probe to study the evolution of cosmic star formation, the reionization of the intergalactic medium, and the metal enrichment history of the universe, since the prompt gamma-ray emission of GRBs should be detectable out to distances z>10. Hitherto, the highest measured redshift for a GRB has been z=4.50. Here we report the optical spectrum of the afterglow of GRB 050904 obtained 3.4 days after the burst. The spectrum shows a clear continuum at the long wavelength end of the spectrum with a sharp cutoff at around 9000 A due to Ly alpha absorption at a redshift of 6.3 with a damping wing. Little flux is present in the waveband shortward of the Ly alpha break. A system of absorption lines of heavy elements at redshift z=6.295 +- 0.002 were also detected, yielding a precise measurement of the largest known redshift of a GRB. Analysis of the Si II fine structure lines suggest a dense metal-enriched environment around the GRB progenitor, providing unique information on the properties of the gas in a galaxy when the universe was younger than one billion years.
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