High resolution FUSE and STIS observations of the bright QSO HE 0226-4110 (zem = 0.495) reveal the presence of a multi-phase absorption line system at zabs(O VI) = 0.20701 containing absorption from H I (Ly alpha to Ly theta), C III, O III, O IV, O VI, N III, Ne VIII, Si III, S VI and possibly S V. Single component fits to the Ne VIII and O VI absorption doublets yield logN(Ne VIII) = 13.89+/-0.11 and logN(O VI) = 14.37+/-0.03. The Ne VIII and O VI doublets are detected at 3.9 sigma and 16 sigma significance levels, respectively. This represents the first detection of intergalactic Ne VIII, a diagnostic of gas with temperature in the range from 5x10(5) to 1x10(6) K. The O VI and Ne VIII are not likely created in a low density medium photoionized solely by the extragalactic background at z = 0.2 since the required path length of ~11 Mpc implies the Hubble flow absorption line broadening would be ~10 times greater than the observed line widths. A collisional ionization origin is therefore more likely. Assuming [Ne/H] and [O/H] = -0.5, the value N(Ne VIII)/N(O VI) = 0.33+/-0.10 is consistent with gas in collisional ionization equilibrium near T=5.4x10(5) K with logN(H)= 19.9 and N(H)/N(H I) = 1.7x10(6). The observations support the basic idea that a substantial fraction of the baryonic matter at low redshift exists in hot very highly ionized gaseous structures.
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