We report new HST/WFPC2 photometry for 10 globular clusters (GC) in M31 observed in F5555W(V) and F814W(I). Additionally we have reanalyzed HST archival data of comparable quality for 2 more GCs. Extraordinary care is taken to account for the effects of blended stellar images and required field subtraction. We thus reach 1 mag fainter than the horizontal branch (HB) even in unfavorable cases. We present the color-magnitude diagrams (CMDs) and discuss their main features also in comparison with the properties of the Galactic GCs. This analysis is augmented with CMDs previously obtained and discussed by Fusi Pecci et al. (1996) on 8 other M31 clusters. We report the following significant results: 1. The locus of the red giant branches give reliable metallicity determinations which compare generally very well with ground-based integrated spectroscopic and photometric measures, as well as giving good reddening estimates. 2. The HB morphologies show the same behavior with metallicity as the Galactic GCs, with indications that the 2nd-parameter effect can be present in some GCs of our sample. However, at [Fe/H] ~ -1.7 we observe a number of GCs with red HB morphology such that the HB type versus [Fe/H] relation is offset from the MW and resembles that of the Fornax dwarf spheroidal galaxy. One explanation for the offset is that they are younger than their MW counterparts by 1-2 Gyr. 3. The Mv(HB)-[Fe/H] relationship has been determined and the slope (~0.20) is very similar to the values derived from RR Lyrae stars in the MW and the LMC. The zero-point of this relation based on the assumed distance modulus (m-M)o(M31)=24.47+/-0.03 is consistent with (m-M)o(LMC)=18.55.
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