On January 10 and 13, 2001, Venus was observed for the first time with an X-ray astronomy satellite. The observation, performed with the ACIS-I and LETG/ACIS-S instruments on Chandra, yielded data of high spatial, spectral, and temporal resolution. Venus is clearly detected as a half-lit crescent, with considerable brightening on the sunward limb. The morphology agrees well with that expected from fluorescent scattering of solar X-rays in the planetary atmosphere. The radiation is observed at discrete energies, mainly at the O-K_alpha energy of 0.53 keV. Fluorescence radiation is also detected from C-K_alpha at 0.28 keV and, marginally, from N-K_alpha at 0.40 keV. An additional emission line is indicated at 0.29 keV, which might be the signature of the C 1s --> pi* transition in CO2 and CO. Evidence for temporal variability of the X-ray flux was found at the 2.6 sigma level, with fluctuations by factors of a few times indicated on time scales of minutes. All these findings are fully consistent with fluorescent scattering of solar X-rays. No other source of X-ray emission was detected, in particular none from charge exchange interactions between highly charged heavy solar wind ions and atmospheric neutrals, the dominant process for the X-ray emission of comets. This is in agreement with the sensitivity of the observation.
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