A full set of calculations is presented for inner-shell n = 2 to 3 photoexcitation of the 16 iron charge states: Fe I through Fe XVI. The blend of the numerous absorption lines arising from these excitations (mainly 2p - 3d) forms an unresolved transition array (UTA), which has been recently identified as a prominent feature between 16 - 17 AA in the soft X-ray spectra of active galactic nuclei (AGN). Despite the blending within charge-states, the ample separation between the individual-ion features enables precise diagnostics of the ionization range in the absorbing medium. Column density and turbulent velocity diagnostics are also possible, albeit to a lesser accuracy. An abbreviated set of atomic parameters useful for modeling the Fe 2p - 3d UTA is given. It is shown that the effects of accompanying photoexcitation to higher levels ($n ge$ 4), as well as the associated photoionization edges, may also be relevant to AGN spectra.