A system of hard rigid rods of length $k$ on hypercubic lattices is known to undergo two phases transitions when chemical potential is increased: from a low density isotropic phase to an intermediate density nematic phase, and on further increase to a high-density phase with no orientational order. In this paper, we argue that, for large $k$, the second phase transition is a first order transition with a discontinuity in density in all dimensions greater than $1$. We show the chemical potential at the transition is $approx k ln [k /ln k]$ for large $k$, and that the density of uncovered sites drops from a value $ approx (ln k)/k^2$ to a value of order $exp(-ak)$, where $a$ is some constant, across the transition. We conjecture that these results are asymptotically exact, in all dimensions $dgeq 2$. We also present evidence of coexistence of nematic and disordered phases from Monte Carlo simulations for rods of length $9$ on the square lattice.
تحميل البحث