Ion-pairing is commonly considered as a culprit for the reduced ionic conductivity in polymer electrolyte systems. However, this simple thermodynamic picture should not be taken literally, as ion-pairing is a dynamical phenomenon. Here we construct model PEO-LiTFSI systems with different degree of ion-pairing by tuning solvent polarity, and examine the relation between the cation-anion distinct conductivity $sigma^rm{d}_{+-}$ and the lifetime of ion-pairs $tau_{+-}$ using molecular dynamics simulations. It is found that there exist two distinct regimes where $sigma^rm{d}_{+-}$ scales with $1/tau_{+-}$ and $tau_{+-}$ respectively, and the latter is a signature of longer-lived ion-pairs which contribute negatively to the total ionic conductivity. This suggests that ion-pairs are kinetically different depending on the solvent polarity, which renders the ion-pair lifetime highly important when discussing its effect on ion transport in polymer electrolyte systems.
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