We consider the stochastic electrokinetic flow in a smooth bounded domain $mathcal{D}$, modelled by a Nernst-Planck-Navier-Stokes system with a blocking boundary conditions for ionic species concentrations, perturbed by multiplicative noise. Several results are established in this paper. In both $2d$ and $3d$ cases, we establish the global existence of weak martingale solution which is weak in both PDEs and probability sense, and also the existence and uniqueness of the maximal strong pathwise solution which is strong in PDEs and probability sense. Particularly, we show that the maximal pathwise solution is global one in $2d$ case without the restriction of smallness of initial data.
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