We cast the quantum chemistry problem of computing bound states as that of solving a set of auxiliary eigenvalue problems for a family of parameterized compact integral operators. The compactness of operators assures that their spectrum is discrete and bounded with the only possible accumulation point at zero. We show that, by changing the parameter, we can always find the bound states, i.e., the eigenfunctions that satisfy the original equations and are normalizable. While for the non-relativistic equations these properties may not be surprising, it is remarkable that the same holds for the relativistic equations where the spectrum of the original relativistic operators does not have a lower bound. We demonstrate that starting from an arbitrary initialization of the iteration leads to the solution, as dictated by the properties of compact operators.
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