Improving the understanding of diffusive processes in networks with complex topologies is one of the main challenges of todays complexity science. Each network possesses an intrinsic diffusive potential that depends on its structural connectivity. However, the diffusion of a process depends not only on this topological potential but also on the dynamical process itself. Quantifying this potential will allow the design of more efficient systems in which it is necessary either to weaken or to enhance diffusion. Here we introduce a measure, the {em diffusion capacity}, that quantifies, through the concept of dynamical paths, the potential of an element of the system, and also, of the system itself, to propagate information. Among other examples, we study a heat diffusion model and SIR model to demonstrate the value of the proposed measure. We found, in the last case, that diffusion capacity can be used as a predictor of the evolution of the spreading process. In general, we show that the diffusion capacity provides an efficient tool to evaluate the performance of systems, and also, to identify and quantify structural modifications that could improve diffusion mechanisms.
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