The odd wheel $W_{2k+1}$ is the graph formed by joining a vertex to a cycle of length $2k$. In this paper, we investigate the largest value of the spectral radius of the adjacency matrix of an $n$-vertex graph that does not contain $W_{2k+1}$. We determine the structure of the spectral extremal graphs for all $kgeq 2, k otin {4,5}$. When $k=2$, we show that these spectral extremal graphs are among the Tur{a}n-extremal graphs on $n$ vertices that do not contain $W_{2k+1}$ and have the maximum number of edges, but when $kgeq 9$, we show that the family of spectral extremal graphs and the family of Tur{a}n-extremal graphs are disjoint.
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