Ultra-hot Jupiters are the hottest close-in exoplanets discovered so far, and present a unique possibility to explore hot and cold chemistry on one object. The tidally locked ultra-hot Jupiter HAT-P-7b has a day/night temperature difference of ~ 2500K, confining cloud formation to the nightside and efficient ionisation to the dayside. Both have distinct observational signatures. We analyse plasma and magnetic processes in the atmosphere of the ultra-hot Jupiter HAT-P-7b to investigate the formation of a thermal ionosphere and the possibility of magnetically coupling the atmospheric gas as the base for an extended exosphere. We show which ions and atoms may be used as spectral tracers, and if and where conditions for lightning may occur within the clouds of HAT-P-7b, evaluate characteristic plasma and magnetic coupling parameters, and a LTE radiative transfer is solved for the ionised gas phase. The ionisation throughout HAT-P-7bs atmosphere varies drastically between day- and nightside. The dayside has high levels of thermal ionisation and long-range electromagnetic interactions dominate over kinetic electron-neutral interactions, suggesting a day-night difference in magnetic coupling. K+, Na+, Li+, Ca+, and Al+ are more abundant than their atomic counterparts on the dayside. The minimum magnetic flux density for electrons for magnetic coupling is B<0.5G for all regions of HAT-P-7bs atmosphere. HAT-P-7bs dayside has an asymmetric ionosphere that extends deep into the atmosphere, the nightside has no thermally driven ionosphere. A corresponding asymmetry is imprinted in the ion/neutral composition at the terminators. The ionosphere on HAT-P-7b may be directly traced by the Ca+ H&K lines if the local temperature is > 5000K. The whole atmosphere may couple to a global, large-scale magnetic field, and lightning may occur on the nightside.
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