AgCl-induced hot salt stress corrosion cracking in a titanium alloy


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The mechanism of AgCl-induced stress corrosion cracking of Ti-6246 was examined at SI{500}{megapascal} and SI{380}{celsius} for SI{24}{hour} exposures. SEM and STEM-EDX examination of a FIB-sectioned blister and crack showed that metallic Ag was formed and migrated along the crack. TEM analysis also revealed the presence of ce{SnO2} and ce{Al2O3} corrosion products mixed into ce{TiO2}. The fracture surface has a transgranular nature with a brittle appearance in the primary $alpha$ phase. Long, straight and non-interacting dislocations were observed in a cleavage-fractured primary $alpha$ grain, with basal and pyramidal traces. This is consistent with a dislocation emission view of the the cracking mechanism.

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