Element diffusion is a key physical process that substantially impacts the superficial abundances, internal structure, pulsation properties, and evolution of white dwarfs. We study the effect of Coulomb separation of ions in the cooling times of evolving white dwarfs, their chemical profiles, the Brunt-Vaisala (buoyancy) frequency, and the pulsational periods at the ZZ Ceti instability strip. We follow the full evolution of white-dwarf models derived from their progenitor history on the basis of a time-dependent element diffusion scheme that incorporates the effect of gravitational settling of ions due to Coulomb interactions at high densities. We find that Coulomb sedimentation profoundly alters the chemical profiles of ultra-massive ($M_*> 1 M_{sun}$) white dwarfs along their evolution, preventing helium from diffusing inward toward the core, and thus leading to much narrower chemical transition zones. As a result, significant changes in the $g$-mode pulsation periods as high as $15 %$ are expected for ultra-massive ZZ Ceti stars. This should be taken into account in detailed asteroseismological analyses of such stars. For less-massive white dwarfs, the impact of Coulomb separation is much less noticeable, inflicting period changes in ZZ Ceti stars that are below the period changes that result from uncertainties in progenitor evolution, albeit larger than typical uncertainties of observed periods.
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