Hydrodynamic simulations of sedimenting dilute particle suspensions under repulsive DLVO interactions


الملخص بالإنكليزية

We present guidelines to estimate the effect of electrostatic repulsion in sedimenting dilute particle suspensions. Our results are based on combined Langevin dynamics and lattice Boltzmann simulations for a range of particle radii, Debye lengths and particle concentrations. They show a simple relationship between the slope $K$ of the sedimentation velocity over the concentration versus the range $chi$ of the electrostatic repulsion normalized by the average particle-particle distance. When $chi to 0$, the particles are too far away from each other to interact electrostatically and $K=6.55$ as predicted by the theory of Batchelor. As $chi$ increases, $K$ likewise increases up to a maximum around $chi=0.5$ and then decreases again to a concentration-dependent constant over the range $chi=0.5-1$, while the particles transition from a disordered gas-like distribution to a liquid-like state with a narrow distribution of the interparticle spacing.

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