We present a measurement of the Hubble constant $H_0$ using the gravitational wave (GW) event GW190814, which resulted from the coalescence of a 23 $M_odot$ black hole with a 2.6 $M_odot$ compact object, as a standard siren. No compelling electromagnetic counterpart has been identified for this event, thus our analysis accounts for thousands of potential host galaxies within a statistical framework. The redshift information is obtained from the photometric redshift (photo-$z$) catalog from the Dark Energy Survey. The luminosity distance is provided by the LIGO/Virgo gravitational wave sky map. Since this GW event has the second-smallest localization volume after GW170817, GW190814 is likely to provide the best constraint on cosmology from a single standard siren without identifying an electromagnetic counterpart. Our analysis uses photo-$z$ probability distribution functions and corrects for photo-$z$ biases. We also reanalyze the binary-black hole GW170814 within this updated framework. We explore how our findings impact the $H_0$ constraints from GW170817, the only GW merger associated with a unique host galaxy. From a combination of GW190814, GW170814 and GW170817, our analysis yields $H_0 = 72.0^{+ 12}_{- 8.2 }~{rm km~s^{-1}~Mpc^{-1}}$ (68% Highest Density Interval, HDI) for a prior in $H_0$ uniform between $[20,140]~{rm km~s^{-1}~Mpc^{-1}}$. The addition of GW190814 and GW170814 to GW170817 improves the 68% HDI from GW170817 alone by $sim 18%$, showing how well-localized mergers without counterparts can provide a significant contribution to standard siren measurements, provided that a complete galaxy catalog is available at the location of the event.
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