This paper studies combinatorial properties of the complex of planar injective words, a chain complex of modules over the Temperley-Lieb algebra that arose in our work on homological stability. Despite being a linear rather than a discrete object, our chain complex nevertheless exhibits interesting combinatorial properties. We show that the Euler characteristic of this complex is the n-th Fine number. We obtain an alternating sum formula for the representation given by its top-dimensional homology module and, under further restrictions on the ground ring, we decompose this module in terms of certain standard Young tableaux. This trio of results - inspired by results of Reiner and Webb for the complex of injective words - can be viewed as an interpretation of the n-th Fine number as the planar or Dyck path analogue of the number of derangements of n letters. This interpretation has precursors in the literature, but here emerges naturally from considerations in homological stability. Our final result shows a surprising connection between the boundary maps of our complex and the Jacobsthal numbers.
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